If the question is how many mg of Mn in 8.18x10^21 atoms of KMnO4 the calulation is
(8.18E21 * 54.93 * 1000) / 6.02E23 =74.6
the way you wrote can be misinterpreted
8.18E21 / 6.02E23* 54.93 * 1000 could be
(8.18E21 / 6.02E23)* 54.93 * 1000 = 74.6 as above
or
8.18E21 / (6.02E23* 54.93 * 1000) = 2.47E-7