May 03, 2024, 05:11:07 PM
Forum Rules: Read This Before Posting


Topic: Reaction Spontanaity  (Read 2962 times)

0 Members and 1 Guest are viewing this topic.

Offline CandyApples

  • New Member
  • **
  • Posts: 3
  • Mole Snacks: +0/-0
Reaction Spontanaity
« on: October 20, 2009, 02:09:28 AM »
The question asks if BaCl2 + H2SO4 is a spontaneous reaction, and what does that tell you about delta g. My prediction is that delta G is positive, hence the reaction is not spontaneous. My logic is that one of the products is 2HCl, which has a pka of -7 while H2SO4 is only -3. Since the disassociation favors HCl, it is more likely that the reactants will not go forward with the reaction, hence delta g is positive. Is this the case, or is my logic mistaken?

Offline Borek

  • Mr. pH
  • Administrator
  • Deity Member
  • *
  • Posts: 27670
  • Mole Snacks: +1801/-410
  • Gender: Male
  • I am known to be occasionally wrong.
    • Chembuddy
Re: Reaction Spontanaity
« Reply #1 on: October 20, 2009, 02:45:35 AM »
Why do you ignore other products?
ChemBuddy chemical calculators - stoichiometry, pH, concentration, buffer preparation, titrations.info

Offline CandyApples

  • New Member
  • **
  • Posts: 3
  • Mole Snacks: +0/-0
Re: Reaction Spontanaity
« Reply #2 on: October 20, 2009, 02:54:42 AM »
Well, BaCl2 is soluble in water, and BaSO4 can precipitate out. I guess I just looked at the high instability of HCl and incorrectly made an assumption.
« Last Edit: October 20, 2009, 03:05:28 AM by CandyApples »

Sponsored Links