Chemical Forums
Chemistry Forums for Students => Organic Chemistry Forum => Topic started by: xshadow on September 09, 2019, 09:42:52 AM
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Hi,I don't understand the last step
First one is a "normal halogenation"
Which reactant should I use to get that alkene and reforming C=C double bond?
Thanks!
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Which reaction, no pictures visible.
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https://imgur.com/gallery/X5s1SnL
Sorry!!
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Reduction with Lithium, Magnesium or Calcium.
Better is to add HI instead of I2 and do E-Reaction with Hydroxide. Side product is the alcohol.
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xshadow,
Please show us your attempt or give us your thoughts before we can help you. That is a Forum Rule (see red link above).
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I ' ve asked you all because nothing come to mind thinking at the reactions seen in org chem1
I have a "" I-C-C-I" structure and I need to take out the two Iodine in order to create a double bond C=C"..
But in which way?
A sn2 reaction on a alkyl halide with an H- (witch whic species? NaBH4 or LiAlH4 ?? I've senn these species in reduction of C=O ,not too much in Sn2 with alkyl halide)as nucleophile can take away the iodium as I-...
And IF only one of the two halide go out I could think in the
Next step in an elimination reaction E1/E2 on the second C-Halide bond
BUT this Sn2 reaction occours on both the C-I bond and I'll get an alkane (so no elimination reaction on the second C-I)
Some help? Thanks all!!!
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Reduction with Lithium, Magnesium or Calcium.
Better is to add HI instead of I2 and do E-Reaction with Hydroxide. Side product is the alcohol.
Reduction using a source of H- nucleophile,like LiAlH4 or NaBH4??
A pseudo Sn2 reaction on boh the C-halide bond?
But then I need to convert a single bond CH-CH in a C=C
Thanks
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With respect to cis- versus trans-alkenes, where does the equilibrium lie?
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With respect to cis- versus trans-alkenes, where does the equilibrium lie?
Obviously trans!!
But as I said before my doubt is about the reactant to use in order to convert I--C-C-I in a C=C bond
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I dont you need any reagent, this type of diiodides are not stable, they collapse into the trans-alkene.
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@OP, When something speeds up a reaction but is not a reactant or product, what is it?