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Chemistry Forums for Students => High School Chemistry Forum => Topic started by: Tezz on August 25, 2020, 07:34:55 AM

Title: Percentage yield above 100%?
Post by: Tezz on August 25, 2020, 07:34:55 AM
Hi all, when I do this question I get a percentage yield above 100% which makes me question whether I am right. Could someone check it over? Thanks

I currently have an answer of 116.86%
Title: Re: Percentage yield above 100%?
Post by: sjb on August 25, 2020, 08:51:11 AM
Can you show your working? 10 lines of text shouldn't be that large to type out (which will also help searches in the future, in case the image breaks)
Title: Re: Percentage yield above 100%?
Post by: Tezz on August 25, 2020, 08:54:34 AM
1/28.1 = 0.035587... mols

Molecular mass of SiCl4 = 28.1+4(35.5)
=170.1

0.035587 x 170.1 = 6.05338g

6.05338/3.5 = 1.729537 g/cm^3

1.729537/1.48 = 1.1686

Therefore, 116.86%
Title: Re: Percentage yield above 100%?
Post by: Borek on August 25, 2020, 08:58:31 AM
You got it reversed.

(not that it makes much sense comparing density with hypothetical density of the product, calculate mass of the product from the data given)
Title: Re: Percentage yield above 100%?
Post by: Tezz on August 25, 2020, 09:00:21 AM
Ah, I thought I might have done that. So it should be 1.48/the other value?

I thought that 1.48 was the theoretical yield of the reaction
Title: Re: Percentage yield above 100%?
Post by: DrCMS on August 25, 2020, 09:02:42 AM
1.48g/ml is the density of the product.
Title: Re: Percentage yield above 100%?
Post by: Tezz on August 25, 2020, 09:04:19 AM
1.48g/ml is the density of the product.
Alright thanks, I’ll go and modify my answer to whatever 1.48/other density comes out as. Appreciate the help
Title: Re: Percentage yield above 100%?
Post by: Borek on August 25, 2020, 12:00:42 PM
Alright thanks, I’ll go and modify my answer to whatever 1.48/other density comes out as. Appreciate the help

You do understand it doesn't make physical sense (even if it produces a correct number)?

Density is not something that can randomly change, for a given substance (and PT) it is always the same.

What matters here is not the density, but mass of the product.
Title: Re: Percentage yield above 100%?
Post by: DrCMS on August 25, 2020, 12:04:39 PM
1.48g/ml is the density of the product.
Alright thanks, I’ll go and modify my answer to whatever 1.48/other density comes out as. Appreciate the help

NO there is no other density in the question and you can not calculate a density of anything from the information given. 

The correct way to solve the problem is:

Title: Re: Percentage yield above 100%?
Post by: Enthalpy on August 26, 2020, 04:44:48 AM
I recommend to write the units each and every time you make a computation, and double-check their consistency.

Secret: professional scientists don't memorize formulas. They compute according to the units.