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Chemistry Forums for Students => Inorganic Chemistry Forum => Topic started by: xshadow on October 08, 2020, 12:04:58 PM

Title: TiCl4 + HCl
Post by: xshadow on October 08, 2020, 12:04:58 PM
What are the species in a  solution of TiCl4  in HCl (not water, avoid hydrolysis reaction)  ?
Ti-Cl are covalent bonds



I check but I only found the TiCl4 reaction with water....

 ???
Title: Re: TiCl4 + HCl
Post by: AWK on October 08, 2020, 12:20:53 PM
Check the internet for hydrochlorotitanic acid H2TiCl6.
Title: Re: TiCl4 + HCl
Post by: xshadow on October 08, 2020, 12:56:07 PM
Quote from: AWK on October 08, 2020, 12:20:53 PM
Check the internet for hydrochlorotitanic acid H2TiCl6.

Thanos.

So when I put HCl  ---> H+ + Cl-.

Some Cl- ions  will coordinate the tetrahedral TiCl4 in order to generate an octahedral complex TiCl62- and  2H+ as counter ions for the anionic complex

Is it correct?
THANKS
Title: Re: TiCl4 + HCl
Post by: AWK on October 08, 2020, 01:15:05 PM
https://books.google.pl/books?id=Pef47TK5NfkC&pg=PA1199&lpg=PA1199&dq=ammonium+hexachlorotitanate&source=bl&ots=W9GF9lG9ZL&sig=ACfU3U3SkbAJoc8To4N9qjVWWlciDR8aIw&hl=en&sa=X&ved=2ahUKEwi-tuXXvqXsAhXPpIsKHXGaDmEQ6AEwB3oECAgQAg#v=onepage&q=ammonium%20hexachlorotitanate&f=false
Title: Re: TiCl4 + HCl
Post by: xshadow on October 08, 2020, 01:25:01 PM
Quote from: AWK on October 08, 2020, 01:15:05 PM
https://books.google.pl/books?id=Pef47TK5NfkC&pg=PA1199&lpg=PA1199&dq=ammonium+hexachlorotitanate&source=bl&ots=W9GF9lG9ZL&sig=ACfU3U3SkbAJoc8To4N9qjVWWlciDR8aIw&hl=en&sa=X&ved=2ahUKEwi-tuXXvqXsAhXPpIsKHXGaDmEQ6AEwB3oECAgQAg#v=onepage&q=ammonium%20hexachlorotitanate&f=false
thanks