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Chemistry Forums for Students => Organic Chemistry Forum => Topic started by: myii on May 16, 2021, 11:16:39 AM

Title: Acid or basic catalysis
Post by: myii on May 16, 2021, 11:16:39 AM
Hi

Could someone please tell me what kind of catalysis is (so if it is specific/general acid catalysis or specific/general base catalysis):

Aal1
Aac2
Bal2

Thankss :)
Title: Re: Acid or basic catalysis
Post by: Borek on May 16, 2021, 11:31:22 AM
Aal1
Aac2
Bal2

1. No idea what these are.

2. Please read the forum rules (https://www.chemicalforums.com/index.php?topic=65859.0). You have to show your attempts at answering the question/solving the problem to receive help, it is a forum policy.
Title: Re: Acid or basic catalysis
Post by: myii on May 16, 2021, 11:40:56 AM
Aal1
Aac2
Bal2

1. No idea what these are.

2. Please read the forum rules (https://www.chemicalforums.com/index.php?topic=65859.0). You have to show your attempts at answering the question/solving the problem to receive help, it is a forum policy.

Ah sorry thanks for letting me know the policy :)

This question is surrounding the topic of acids and bases - Specific acid catalysis, General acid catalysis, Specific Base catalysis and General Base catalysis

So Aal1, Aac2, Bal2 are types of ester hydrolysis

Aal1 - a type of ester hydrolysis which is acid catalyzed, alkyl-oxygen cleavage and the rate determining step is unimolecular
Aac2 - a type of ester hydrolysis which is acid catalyzed, acyl-oxygen cleavage and the rate determining step is bimolecular
Bal2 - a type of ester hydrolysis which is basic catalyzed, alkyl-oxygen cleavage and the rate determining step is bimolecular

So my view is that:
Aal1 could be specific acid catalysis
Aac2 could be specific acid catalysis
Bal2 could be general acid catalysis

Is this correct anyone? :) thanks
Title: Re: Acid or basic catalysis
Post by: rolnor on May 16, 2021, 01:17:02 PM
https://www.slideshare.net/mohdsakharkar/acid-base-catalysed-ester-hydrolysis
Title: Re: Acid or basic catalysis
Post by: myii on May 18, 2021, 08:44:31 AM
https://www.slideshare.net/mohdsakharkar/acid-base-catalysed-ester-hydrolysis

Thanks for this :) but would Aal1 be specific acid catalysis, Aac2  be specific acid catalysis and Bal2  be general acid catalysis?