Chemical Forums
Chemistry Forums for Students => Organic Chemistry Forum => Topic started by: ch_wsc on October 17, 2006, 05:33:00 AM
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hi , I am sorry to bother u all with a simple question
I am asked what the stereochemistry of 1,2dibromocyclopentane produced by the reaction of cyclopentene and Br2
I know the 2 bromine atoms will go to opposite sides of 2 carbons but i don't know why it's tran but not anti
thx for any explanation
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When you consider alicyclic compounds, cis means the substituents are on the same side, while trans isomer has one over and the other under the cyclic structure (http://en.wikipedia.org/wiki/Cis-trans_isomerism).
Anti and syn don't refer to a product but to a reaction (i.e. syn-addition).
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Anti and syn don't refer to a product but to a reaction (i.e. syn-addition).
That's not true. For example, the two diastereomeric products of an aldol reaction are typically referred to as anti and syn.
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normally anti and syn would describe the conformation as in syn-periplanar, syn-clinical, anti-clinical, anti-periplanar (if those are also the English terms)
I think it's ok to call the product anti. in a ring also trans works. maybe anti makes you think the bond can rotate, i don't know.