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Chemistry Forums for Students => High School Chemistry Forum => Topic started by: yerbutnobutyer on March 28, 2005, 09:53:09 AM

Title: the total percentage error
Post by: yerbutnobutyer on March 28, 2005, 09:53:09 AM
hello! ;D
i was wondering if anyone knew how to calculate the TOTAL % error. ive just finished a titration and im writing my analysis, ive calculated the individual % errors for each piece of equipment that was used eg:pipette. However i dont know how to calculate the overall % error :-\. Id be really grateful for any help.
thanks sarah x ;)
Title: Re:the total percentage error
Post by: Mitch on March 28, 2005, 10:49:18 AM
look up something called "error propagation".
Title: Re:the total percentage error
Post by: Donaldson Tan on April 02, 2005, 05:53:16 PM
given A = B x C, then the error of A is:
dA/A = dB/B + dC/C
Title: Re:the total percentage error
Post by: mithrilhack on April 02, 2005, 11:39:38 PM
you expect him to do derivatives?
Title: Re:the total percentage error
Post by: Mitch on April 02, 2005, 11:46:37 PM
You can't do error propagation without derivatives, more generally partial derivatives.
Title: Re:the total percentage error
Post by: hmx9123 on April 03, 2005, 05:39:00 AM
If you know what the individual errors are, you can add them up without doing derivatives in most cases.  Unfortunately, it involves some math that I can't recall at the moment.  There's different procedures for additive, divisive, etc. errors, so it depends on how you're manipulating the data.  Look in a statistics book or just search the web for 'additive errors' or 'adding errors'.  It's in my analytical chem book, but that thing is 2100 miles away from me right now (a worthy place for it).
Title: Re:the total percentage error
Post by: Mitch on April 03, 2005, 03:16:34 PM
You typically just can't add errors though. Additive error addition involves the square root( of the sum of the individual errors individually squared.) But, it all depends on the setup of course.
Title: Re:the total percentage error
Post by: pkothari13 on April 03, 2005, 10:31:16 PM
why not take the average of all your experimental values needed to titrate your solution and then find the percent error from the literature value.

or try standard deviation

hope that kinda helped
Title: Re:the total percentage error
Post by: sammyr on April 14, 2005, 04:38:38 PM
percentage error =       (Error / Reading) x 100
Title: Re:the total percentage error
Post by: arcanineghost on April 17, 2005, 09:52:09 AM
at our high school you calculate the percent error by taking the absolute value of the actual/theoretical value - experimental data all divided by the actual/theoretical value times 100%

Looks like this:

|actual-experimental|
-------------------------   x 100% = experimental percent error
          actual


hope that helps  :)