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Chemistry Forums for Students => Undergraduate General Chemistry Forum => Topic started by: Workaholic on April 24, 2005, 09:46:30 AM

Title: Writing chemical equations
Post by: Workaholic on April 24, 2005, 09:46:30 AM
I am learning how to write balanced chemical equations.  I have mastered the art of balancing and writing equations.  I experience no difficulty writing them out from word equations (and vice versa)    

I also know how to balance and write redox and half ionic/ionic equations.

However Im having trouble when given the task of writing chemical equations when NO PRODUCTS are given to me.  I can't seem to work out what is produced.  I am fine when asked to write equations when the reactants and products are stated.

Are their rules about what is produced?

My tutor gave me general rules as follows:
1) Acid + Reactive Metal = Salt + H20
2) Acid + Base = Salt + H20
3) Acid + Metal Carbonate + Salt + H20 +CO2

But they don't help me with other problems such as:
1)SiCl4 + H20 = ??

2)Ca(OH)2 + 2NH4Cl = CaCl2 + 2NH4(OH) (is this rite, cus im guessing)

Please help as it is really holding me back!

 
Title: Re:Writing chemical equations
Post by: Borek on April 25, 2005, 05:50:12 AM
Are their rules about what is produced?

That's what the chemistry is all about ;)

There are general rules, but there are also tons of exclusions.
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My tutor gave me general rules as follows:
1) Acid + Reactive Metal = Salt + H20
2) Acid + Base = Salt + H20
3) Acid + Metal Carbonate + Salt + H20 +CO2

You did a mistake writing third rule, but these are OK and should be helpfull.

In other cases you just have to know, or you have to develop some 'chemical intuition' - whatever it means.

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1)SiCl4 + H20 = ??

My intuition tells me - either nothing, or hydrolysis to SiO2 plus HCl. Probably the latter.

Quote
2)Ca(OH)2 + 2NH4Cl = CaCl2 + 2NH4(OH) (is this rite, cus im guessing)

More or less OK. To be precise I will write not NH4(OH) but NH3(aq) + H2O.

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Please help as it is really holding me back!

Don't bother too much - if there will be a closed set of rules describing what are reaction products, chemists will be an extinct species :)
Title: Re:Writing chemical equations
Post by: AWK on April 25, 2005, 07:06:02 AM
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1) Acid + Reactive Metal = Salt + H20
Above is a ore serious mistake - hydrogen should be instead of water

Quote
2)Ca(OH)2 + 2NH4Cl = CaCl2 + 2NH4(OH)
Ca(OH)2 is poorly soluble in water, but this is a strong base, ammonia is a weak base, hence reaction proceeds, even quantitatively, when solution is warmed to remove ammonia. This is an ammonia regeneration process in Na2CO3 production by a Solvay method.