Chemical Forums
Chemistry Forums for Students => Organic Chemistry Forum => Topic started by: cfr on November 09, 2010, 07:48:45 PM
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hello,
i have some lab questions that I am confused about I hope you can help.
i have to arrange halides in order of decreasing reactivity toward ethanol silver nitrate
1-chlorobutane
2-chlorobutane
2-chloro-2-methylpropane
allyl chloride
benzyl chloride
chlorobenzene
also for reactivity with sodium iodide
1-bromobutane
2-bromobutane
2-bromo-2-methylpropane
allyl bromide
benzyl bromide
bromobenzene
thank you
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hello,
i have some lab questions that I am confused about I hope you can help.
i have to arrange halides in order of decreasing reactivity toward ethanol silver nitrate
1-chlorobutane
2-chlorobutane
2-chloro-2-methylpropane
allyl chloride
benzyl chloride
chlorobenzene
also for reactivity with sodium iodide
1-bromobutane
2-bromobutane
2-bromo-2-methylpropane
allyl bromide
benzyl bromide
bromobenzene
thank you
These are all nucleophillic displacement reactions. The order is the same for both nucleophiles, nitro and iodide.
To start you off, chloro/bromobenzene is the least reactive towards both reagents
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I might be able to give a hint, go back and look at the mechanisms in your text book and pay particular attention to steric crowding and the stability of carbon cations; also, it's always helped me to draw out the molecule. If that doesn't really help, post again and call me butt head. I'd be happy to explain in greater detail. ;D