Chemical Forums
Chemistry Forums for Students => Organic Chemistry Forum => Organic Spectroscopy => Topic started by: Bidagdha_TADIR on April 26, 2014, 03:25:17 AM
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I am learning the basics of NMR this year. One of the books recommended to me is "Introduction to spectroscopy" by Donald L. Pavia. While reading the book, I learned that the older instruments were designed to keep the rf frequency constant and would vary the external magnetic field strength to cause absorption of energy by different hydrogen nuclei.
But chemical shift is measured in delta scale as -
[tex] \frac {(\nu_s - \nu_{TMS})}{(Spectrometer frequency in MHz)} [/tex]
where,
[tex] \nu_s = Resonance frequency of that nuclei [/tex]
[tex] \nu_{TMS} = Resonance frequency of hydrogen nuclei in TMS [/tex]
Every term in the equation is related to frequency. So, how an instrument measuring the magnetic field strength required to cause the absorption would calculate the chemical shift by above definition ? Is something like the following equation would be used -
[tex] \frac {(B_s - B_{TMS})}{(Spectrometer frequency in MHz)} [/tex]
Where,
Bs = Magnetic field required to cause absorption by that nuclei
BTMS = Magnetic field required to cause absorption by hydrogen nuclei in TMS
This seems unlikely because the the change in the magnetic field required would be very small (I think 1-2 Gauss).
(I am extremely sorry if the equations do not appear in a legible form, I tried to see the preview but LaTex form would not show in the preview).