Chemical Forums

Chemistry Forums for Students => Undergraduate General Chemistry Forum => Topic started by: tantan on June 29, 2006, 05:54:24 AM

Title: calculation of buffer ph
Post by: tantan on June 29, 2006, 05:54:24 AM
hello i have my biochemistry final tomorrow and i need your help guys ...

if some 1 can help me live online its better for me, my msn address is : atanas_zaher@hotmail.com

we can chat and u can help me,

first problem : calculation of buffer ph

** 0.81M NH4Cl , with 0.35M NH3 ,(Kb of NH3 is 1.8*10-5 ) (1.8* ten to the power of minus five ) - what is the ph of the buffer
1)8.89
2)8.82
3)9.62
4)5.11

one of these answers , i just dont know how to do it :( :'(

the second problem is :

*** an ionic crystal of 2 grams, in 400 grams water has a freezing point of 0.308c (celzius) ,The molal freezing point of water is 1.86c (celzius) , its known that this ionic crystal dissociates into 2 electrolytes , what is the molar mass ?

1)40
2)60
3)80
4)120
5)140

and last question i have is not calculation :
what are the minor bases of RNA ?
1) 6-Methyl Adenine
2) 7-Methyl Guanine
3) 2-Methyl Cytosine
4) 2-N- Methyl Guanin
5) HydroxyLamine

Thanks So Much For Your Help And COoperation :(
atanas :)
atanas_zaher@hotmail.com



Title: Re: A Calculation problem please help urgent!
Post by: Borek on June 29, 2006, 06:47:32 AM
first problem : calculation of buffer ph

** 0.81M NH4Cl , with 0.35M NH3 ,(Kb of NH3 is 1.8*10-5 ) (1.8* ten to the power of minus five ) - what is the ph of the buffer

Calculation of buffer pH (http://www.chembuddy.com/?left=pH-calculation&right=pH-buffers-henderson-hasselbalch)
Title: Re: A Calculation problem please help urgent!
Post by: tantan on June 29, 2006, 09:12:50 AM

i still didnt get how can i sove the calculation by the equation of buffer ph

??
Title: Re: A Calculation problem please help urgent!
Post by: Borek on June 29, 2006, 10:18:30 AM
You have Henderson-Hasselbalch equation at the link provided, you have concentration of the acid and conjugated base given in the question, you have Kb value - all you have to do is to enter these values into the equation.
Title: Re: A Calculation problem please help urgent!
Post by: tantan on June 29, 2006, 12:13:30 PM
what about the other problems ? anyone knows how to solve them ?
Title: Re: calculation of buffer ph
Post by: sdekivit on July 02, 2006, 03:02:19 AM
the second one is freezingpoint depression

delta delta Tf = -Kf * m * i

(delta Tf = freezingpoint depression, Kf = molal freezingpoint depression constant, m = molality of solute and i = amount ions after solution / moles of solute before solution)

now fill in this formula and you will find your answer.