emperical formula- formula of a substance written with the smallest integer (whole number) subscripts.
here's an example:
a sample weighing 1.587 g is found in .483 g Nitrogen
and 1.104 g Oxygen.
1. You first start of by changing the grams into mole. You can do this by diving the grams givin by the atomic weight. in this case, Nitrogen = 14 and Oxygen = 16.
this leaves you with this
.483/14 = .0345 moles of Nitrogen
and
1.104/16 = .06900 moles of Oxygen
2. take the smallest numer (in this case .0345) and divide it by both numbers
this should look like
(Nitrogen) .0345/.0345 = 1
and
(Oxygen) .06900/.0345 = 2
3. the ratio of N atoms to the number of O atoms is 1 and 2. Hence the answer is
NO2
hope I helped,
Shinigami