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Topic: hess's law  (Read 2417 times)

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Offline KitCh

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hess's law
« on: November 02, 2009, 08:00:38 PM »
Here is the problem:




Here is the correct reaction set arrangement:




Comments and questions:

* I understand why Reaction A was switched.
* I understand why Reaction B was multiplied by 2.
* What happened to 6O2 from reaction A? How did it get canceled?
* Why was reaction C reversed? Wasn't 3O2 part of the reactant? If so, why was it reversed to now have 3O2 in the solution?


Thanks.
« Last Edit: November 02, 2009, 08:10:47 PM by KitCh »

Offline orgoclear

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Re: hess's law
« Reply #1 on: November 03, 2009, 01:08:46 AM »
Ignore the solution they have provided and think on your own

In the final reaction you need 2B2O3 on the right so, you need to flip A so and multiply by 2. This gives 2B2O3 on the right.

After flipping A you get 2B2H6 on the left which is not there in the final reaction. So, you need to multiply B by 2 so that the B2H6 can cancel out.

In flipping A we get 3H2O(g) on the right. So, flip D and multiply by 3 to cancel out the H2O(g). Now in flipping D we get 3H2O(l) on the right so to cancel it flip C and multiply by 3.

Now if you add everything you should get the required reaction.

Now you should be able to understand what has been done in the solutions

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