iodine vapours contains 40% by volume of I atoms.
I2(g)--->(reversibly) 2 I(g)
I
2 molecules and I atoms reversibly interchange between molecule-atom. I atoms constantly change into I
2 molecules and I
2 molecules constantly change into I atoms. Iodine vapors consist of 40% I atoms. This means that 40% of the vapor particles are I atoms and the other 60% are I
2 molecules.