May 23, 2024, 05:47:11 PM
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Topic: Is there a limited amount of "moves" you can do per step in reaction mechanisms?  (Read 2270 times)

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Offline Fzang

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Sometimes there are reactions written in like 10 steps, where I could easily weed out some of the unnecessary steps (such as writing up a whole step for a proton dissociating alone).



So is the second way of doing it accepted as well, or do you need to write up intermediates sometimes? Can I technically put in as many arrows as I want, as long as it still makes sense (as well as being clear and understandable, of course! I'm not talking about 30 arrows per step  :D) with regard to currently added reagents, catalysts etc.?

Offline pfnm

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Yes I've been wondering about some of the formalities of writing reaction mechanisms as well. This is a good question; I feel like I'm picking up bits and pieces of writing mechanisms, from lectures, lecture notes, texts and elsewhere. But are there a list of formal rules for mechanisms? Can condense steps like Fzang has asked?

Offline Honclbrif

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http://www.springer.com/chemistry/organic+chemistry/book/978-0-387-95468-4

Skipping steps can be a slippery slope. Frequently the steps you skip are trivial and you know exactly what happened, but there's that 1% of times that what you skipped actually makes a difference.

I'll usually skip obvious proton transfer steps, or tetrahedral intermediates, but that's about it. If you're writing the mechanism for a class or a test, don't skip anything.
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