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Topic: Balancing REDOX reactions using oxidation number method  (Read 25376 times)

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Nyki

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Balancing REDOX reactions using oxidation number method
« on: April 03, 2006, 09:38:45 PM »
I really need help balancing redox reactions using the oxidation number method.
If someone could run through an example and the proper steps it'd be a great help, thanks so much!

*example you could do, but anything would help*
I2 + HOCl -> IO3- + Cl- (acidic)

hay

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Re:Balancing REDOX reactions using oxidation number method
« Reply #1 on: April 04, 2006, 12:23:59 AM »
Let's start with I2. Note IO3- is singly charged, that's to prevent confusion.

I2     -->  IO3-

Firstly, balance the number of I needed.

I2    --> 2IO3-

Secondly, balance the number of O needed with H2O

I2 + 6H2O --> 2IO3-

Thridly, balance the H needed by adding H+

I2 + 6H2O --> 2IO3- + 12H+

Forth, balance the charge by adding electrons

I2 + 6H2O --> 2IO3- + 12H+   +   10e --(1)

If it's an alkaline condition, we would have to add OH- to balance H+, take away the extra H2O on both side followed by adding electrons.

Do the same for HOCL,
You would get

HOCL + H+  + 2e --> Cl- + H2O -- (2)

Last step, we summarise the equation by balancing the electrons. In this case, equation (2) needs 5 times the electrons. So

5HOCL + I2 + H2O + --> 7H+  +  5Cl- + 2IO3-

Offline Borek

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Re:Balancing REDOX reactions using oxidation number method
« Reply #2 on: April 04, 2006, 03:21:50 AM »
Forth, balance the charge by adding electrons

I2 + 6H2O --> 2IO3- + 12H+   +   10e --(1)

hay: while that's correct (charge must be balanced just as atoms are) it has nothing to do with oxidation numbers, it is so called half-reaction method.

Nyki: search forums, this question was posted many times before.
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hay

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Re:Balancing REDOX reactions using oxidation number method
« Reply #3 on: April 04, 2006, 11:28:30 AM »
Oops, thought that's what he meant  :-X

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