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Substitutions involving the trifluoromethanesulfonyl group leaving have helped me twice at different points in my career.
I used trimethylsilyl trifluoromethanesulfonate and tetrabutylammonium iodide in place of TMSI. I was trying to remove the methyl ester groups from a very labile phosphate ester. TMSI is not the easiest compound with which to work.
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