April 28, 2024, 08:34:05 PM
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Topic: Trouble finding an equation that matches experimental situation [NaOH + CuSO4]  (Read 854 times)

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Offline AqueleBurro

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Hey guys, this is my first post here. If anyone can help me, I had an experiment some time ago where I had to find out what the sample was through the observation of its reactions with some other compounds. The observations were:
- The sample is a strong alkali.
- When the sample was mixed with a solution of CuSO4, it reacted forming a blue precipitate.
- When the resulting sample was mixed with a concentrated solution of ammonia, it turned dark blue.
My guess is that the sample is NaOH and that the reactions were:
2NaOH + CuSO4 = Cu(OH)2 + Na2SO4
Cu(OH)2 + Na2SO4 + 4NH3 = [Cu(NH3)4(H2O)]SO4 + Na2O
Is this correct? I am almost sure that the sample is indeed NaOH, but I am not sure about the equations... Please, lemme know what you guys think and sorry for any grammar mistakes :s

Offline Borek

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First equation is OK, second - not so. You don't need the Na2SO4 on the left, it was just a spectator. Then, you put Na2O on the products side - would it survive in water?
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Offline AWK

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You run the reaction in an aqueous solution.
The complex is well soluble in water, so it's better to write ionic reactions. To be precise - the complex ion in water contains two coordinated water molecules and only one water molecule in solid-state.
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