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Topic: free radocals  (Read 5257 times)

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Offline profmsg

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free radocals
« on: August 25, 2006, 06:04:17 PM »
can anyone give me some idea or link for the information on :

free radical: production, stability, conformations, solvent effects, abstraction, addition reactions, rearrangements. Radicals in synthesis: alkane halogenations, radical oxidations
thanks

Offline Borek

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Re: free radocals
« Reply #1 on: August 25, 2006, 06:21:39 PM »
Google: 93,700,000 hits for free radical. Have you checked at least one of them?
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Offline profmsg

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Re: free radocals
« Reply #2 on: August 25, 2006, 06:28:22 PM »
i know how to do google search and out of 93007000000000 searches, most of them are bull**it ..if u don't have any specific answer then don't waste your time!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!
cheeeeeeers

Offline profmsg

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Re: free radocals
« Reply #3 on: August 25, 2006, 06:41:19 PM »
 i need these things in prospect of organic chemistry.....which i am not able to find in detail...specially ,,,,,the production..
thanks...

Offline Mitch

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Re: free radocals
« Reply #4 on: August 25, 2006, 07:07:05 PM »
Any text on physical organic chemistry will have a whole chapter relating to radical chemistry. I recommend Lowry&Richardson. Although, you attitude could use more work as well.
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abk

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Re: free radocals
« Reply #5 on: August 25, 2006, 07:11:25 PM »
Hi,
   I found out these links on google. I think it will answere your query or atleast give you basic understanding of radicals in organic chemistry and their reactions.

http://www.chemguide.co.uk/mechanisms/frmenu.html
http://chemistry2.csudh.edu/rpendarvis/Radicals.html
www.iupac.org/publications/pac/1997/pdf/6902x0241.pdf
http://www.cem.msu.edu/~reusch/VirtTxtJml/nonionic.htm#rad1

Don't mind but your question is specific. you want to know everything about free radicals so best thing to do is to start with some basic organic chemistry book like Solomons or Morrison and Boyd. Then move on to advanced chemistry books dealing specifially with free radicals. Following are some books which might be usefull.

P. Renaud and M. Sibi, Ed. "Radicals in Organic Synthesis" (2 volume set), Wiley-VCH, Weinheim, 2001.
M. J. Perkins "Radical Chemistry" Ellis, Horwood, New York, 1994.
B. Giese "Radicals in Organic Synthesis: Formation of Carbon-Carbon Bonds" Pergamon, Oxford, 1986.
D. P. Curran, N. A. Porter, B. Giese, "Stereochemistry of Radical Reactions," VCH, Weinheim, 1996.

Best of luck.

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