It can't - it means that the degeneracy is removed.
An isolated PO43- ion has Td symmetry, and some of its vibrational modes will be triply degenerate. But if you put the ion into a crystal environment of lower symmetry, where you cannot have triple degeneracies, then this mode must split into an A and an E, or possibly three As. These will generally have similar, but not identical, energies, leading to a splitting of the band in the IR spectrum.