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Topic: Which molecule has a higher boiling point and how can I know it?  (Read 879 times)

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Offline yuheng_wu

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Which molecule has a higher boiling point and how can I know it?
« on: December 17, 2020, 11:51:03 AM »
CH3CH2OH and CH3COOH
How do I know which atom is the higher boiling point? The only thing I understand is that these molecules both have hydrogen bonds, but what do I do next to differentiate them?
Is it correct to say that the relative molecule mass of CH3COOH (=48) is higher than the relative molecuul mass of CH3CH2OH (=46) and that therefore the boiling point of CH3COOH is higher?
Also you can say that CH3COOH has stronger/more dipole dipole interactions between the COOH group, while CH3CH2OH only has the single dipole dipole interaction of H and O (=hydrogen bond). Is this method of reasoning correct?
« Last Edit: December 17, 2020, 12:10:01 PM by yuheng_wu »

Offline chenbeier

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Re: Which molecule has a higher boiling point and how can I know it?
« Reply #1 on: December 17, 2020, 12:29:17 PM »
Molar mass of acetic acid is 60 g/mol. Ethanol has 46 g/mol . The acid has stronger hydrogen bond to 2 oxygen possible . The alcohol has only one weak one.

Please don't  post same topic under different questions.
« Last Edit: December 17, 2020, 12:48:24 PM by chenbeier »

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