What are you going to get from this experiment? The pH of the NaHCO3 solution is about 8, the pH of the CaCl2 solution is 4-8 depending on the preparation method. Depending on the molar ratios you will get an intermediate pH. A white precipitate will form upon heating. Phenolphthalein will remain colorless, red cabbage juice will change color slightly.
Pour some NaHCO3 solution into the test tube, add phenolphthalein and start heating. At temperatures over 50°C, the solution turns pink. This can be done in a glass of hot water. This reaction is irreversible.