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Topic: Determination of Equilibrium Constant  (Read 2626 times)

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Offline Buddy_123

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Determination of Equilibrium Constant
« on: January 31, 2021, 03:51:36 AM »
Question: A student mixes 5.00mL of 2.00x10-3M Fe(NO3)3 with 5.00mLof 2.00x10-3M KSCN. She finds that in the equilibrium mixture the concentration of FeSCN2+ is 1.40x10-4M. Find K for reaction Fe3+(aq)+SCN-(aq)=FeSCN2(aq).

MY work: Fe3+=(.005)(2.00x10-3)=1x10-5

1x10-5-1.40x10-6=8.6x10-6
SCN^-=1x10-5 & 8.6x10-6

*Both Fe and SCN are the same numbers.
M=8.6x10-6/.01=0.00086

K==1.4x10-4/(0.00086)2
K=189

Can someone let me know if it looks right? I'm not sure if the number is too big and I want to make sure it is correct before I work on part B. Thank You!


Offline AWK

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Re: Determination of Equilibrium Constant
« Reply #1 on: January 31, 2021, 04:09:47 AM »
Good result.
Calculations can be shortened - dilution twice, concentration two times lower.
AWK

Offline Orcio_87

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Re: Determination of Equilibrium Constant
« Reply #2 on: March 09, 2021, 05:15:02 PM »
Quote
Question: A student mixes 5.00mL of 2.00x10-3M Fe(NO3)3 with 5.00mLof 2.00x10-3M KSCN. She finds that in the equilibrium mixture the concentration of FeSCN2+ is 1.40x10-4M. Find K for reaction Fe3+(aq)+SCN-(aq)=FeSCN2(aq).

Initial concentration of Fe3+ and SCN- (after adding solutions altogether) = 1 x 10-3 M

Concentration of Fe3+ and SCN- after reaction:

1 x 10-3 M - 0,14 x 10-3 M = 0,86 x 10-3 M

Thus

K = 0,14 x 10-3 M / [0,86 x 10-3 M]2 = 189

Good answer.

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