[Bolaf7654ggsf]

I would like to know if high pressure is good for homolysis.

Acording to chemical balance rules, if you making two substances from one (decomposition) (you have one mole of substance, and after the reaction you have two) high pressure is bad, but can we apply this on radicals? If so, low pressure is good for homolysis.

But

I consider second option - like in pressure cooker the boiling point is lower when pressure is high - so I quess, that if you increase pressure, lower temperature is needed for homolysis.

I cannot figure out which of theese options is correct, can you help me?

Thanks

[mjc123]

The boiling point is higher when the pressure is high.

[AWK]

Acording to chemical balance rules, if you making two substances from one (decomposition) (you have one mole of substance, and after the reaction you have two)

Not a very precise statement. Imagine the thermal decomposition of CS₂ or HgO.