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Topic: No trans stereoisomers  (Read 4349 times)

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Offline english

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No trans stereoisomers
« on: October 09, 2006, 03:09:58 PM »
Alkenes with fewer than 8 carbons cannot exist as trans stereoisomers.  My book just says it's because a ring with fewer than 8 carbons simply cannot support this configuration.

I know that, for example, cyclohexene cannot exist as a trans isomer because it would look something like this:



So my question is, if cyclohexene was disubstituted it would not exist as a trans isomer either?

-Thanks
« Last Edit: October 09, 2006, 04:05:51 PM by k.V. »

Offline Dan

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Re: No trans stereoisomers
« Reply #1 on: October 09, 2006, 06:51:50 PM »
I'm pretty sure that cyclo-octene can exist in the trans configuration that you posted.

As a side note, it is worth pointing out that Trans-cyclo-octene is chiral.

Try to draw or make a model of trans cyclohexene... It's really, really strained -> doesn't happen.
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