[lukas.stib]

Hello chemists,

I want to ask you how much anhydrous zinc chloride should I use in Lucas´ reagent for the synthesis of 1,3-dichloropropane from 100 g of 1,3-propanediol and 96 g of HCl according to stoichiometry? Or not use ZnCl2 as catalyst for synthesis of 1,3-dichloropropane? Of course, I know that I will have to convert 96 g HCl to 35% hydrochloric acid.

Thank you, Lukáš S.

[rolnor]

You need excess HCl with equimolar ZnCl2,
https://en.wikipedia.org/wiki/Lucas%27_reagent

I dont know if its so good to make primary chlorides?

[lukas.stib]

OK, thank you.