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Offline Q

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Needful aid with a task!
« on: July 01, 2021, 10:20:27 AM »
An organic compound contains 21,20% carbon, 5,30% hydrogen and the rest is arsenic and oxygen. From 0,500 grams of that compound was obtained 0,802 grams of magnesium ammonium arsenate, MgNH4AsO4. Calculate the mass fraction of arsenic and oxygen in that organic compound and its empirical formula.
Solution: w(As)=66,30%, w(O)=7,20%, C4H12As2O
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My attempt:

w(As+O)=73,5%

CaHbAscOd + X :rarrow: MgNH4AsO4 + Y
M(CaHbAscOd):M(MgNH4AsO4)= m(MgNH4AsO4):m(CaHbAscOd)
M(CaHbAscOd) = M(MgNH4AsO4)*m(MgNH4AsO4)/m(CaHbAscOd)=290,741

N(C, CaHbAscOd)=w(C, CaHbAscOd)*M(CaHbAscOd)/M(C)=4,846
N(H, CaHbAscOd)=w(H, CaHbAscOd)*M(CaHbAscOd)/M(H)=15,257

I have no clue what should my proceeding step be, even though my calculations aren't correct.
Thank you in advance!

Offline Borek

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Re: Needful aid with a task!
« Reply #1 on: July 01, 2021, 11:27:54 AM »
How many grams of As in the produced magnesium ammonium arsenate?
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Online mjc123

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Re: Needful aid with a task!
« Reply #2 on: July 01, 2021, 11:46:32 AM »
Quote
M(CaHbAscOd):M(MgNH4AsO4)= m(MgNH4AsO4):m(CaHbAscOd)
This is true only if c = 1. Do you understand why?

Offline Q

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Re: Needful aid with a task!
« Reply #3 on: July 01, 2021, 01:23:34 PM »
Quote
M(CaHbAscOd):M(MgNH4AsO4)= m(MgNH4AsO4):m(CaHbAscOd)
This is true only if c = 1. Do you understand why?

Yes, I do understand, even though it isn't mentioned in the task it was my only idea how to slove it

Offline Q

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Re: Needful aid with a task!
« Reply #4 on: July 01, 2021, 01:25:13 PM »
How many grams of As in the produced magnesium ammonium arsenate?
I have translated the question word by word. Even my professor was stumbled with this task, hence I asked about it here

Offline Borek

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Re: Needful aid with a task!
« Reply #5 on: July 01, 2021, 01:29:28 PM »
How many grams of As in the produced magnesium ammonium arsenate?
I have translated the question word by word. Even my professor was stumbled with this task, hence I asked about it here

You missed the point - it is a trivial thing to calculate, and it will tell you what is mass percentage of As in the compound.
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