January 17, 2022, 07:37:37 PM
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Topic: How does perchloric acid react with piperidine?  (Read 310 times)

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Offline Meter

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How does perchloric acid react with piperidine?
« on: January 03, 2022, 08:52:21 AM »
Hi.

I was wondering how this reaction would evolve.

Is it simply:

ClO3OH  + C5H11N :rarrow: [C5H11NH]+ + 2 O2 + Cl-


Offline Borek

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Re: How does perchloric acid react with piperidine?
« Reply #1 on: January 03, 2022, 11:08:30 AM »
And not just protonated piperidine and ClO4-?
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Offline Meter

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Re: How does perchloric acid react with piperidine?
« Reply #2 on: January 03, 2022, 11:19:14 AM »
And not just protonated piperidine and ClO4-?
Some context: I'm grading some reports where this reaction occurs, and several of my students wrote it as this without citing any reference. My initial guess was also what you wrote, but I was wondering if something strange happened when working with such strong acids.

Offline wildfyr

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Re: How does perchloric acid react with piperidine?
« Reply #3 on: January 03, 2022, 11:21:43 AM »
perchlorate salts are usually pretty stable...

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