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Topic: Carbonyl Reduction to CH2  (Read 848 times)

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Offline tayiqali

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Carbonyl Reduction to CH2
« on: March 09, 2022, 10:19:48 PM »
Please correct me if I'm wrong but book show that you can reduce C=O of aldehydes and ketones (not esters...etc Right?) to CH2 with wolff kishner/clemmensen, but some books also show that it is possible with H2/pd.

But wouldn't H2/pd reduce it to alcohols? or does it only reduce aromatic C=O to ch2?
Please can someone clear this up? Thanks alot

Offline rolnor

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Re: Carbonyl Reduction to CH2
« Reply #1 on: March 09, 2022, 11:38:30 PM »
Aromatic C=O? Whats that? Do you mean benzaldehyde, bensophenone etc.?
You can reduce carbonyls by hydrogenation and if the carbonyl is alpha to a aromatic ring I guess you reduce it further to a CH2. I have never used this, I think its not very common.

https://chem.libretexts.org/Bookshelves/Organic_Chemistry/Organic_Chemistry_I_(Cortes)/21%3A_Hydride_Reactions/21.07%3A_Reduction_of_Carbonyl_Compounds_and_Acid_Chlorides_Through_Catalytic_Hydrogenation

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