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Topic: Can Rhodium(III) react with imidazole?  (Read 1446 times)

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Offline hwg1994

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Can Rhodium(III) react with imidazole?
« on: April 30, 2022, 03:28:14 AM »
Hello everyone, just wondering can Rhodium Chloride react with imidazole or benzeimidazole?
RhCl3*xH2O, imidazole ore benzeimdazole

Offline hwg1994

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Re: Can Rhodium(III) react with imidazole?
« Reply #1 on: April 30, 2022, 04:01:22 AM »
from my understand, Rh(III) can coordinate with pyridine, since there is a  pyridine like nitrogen in imidazole, is it possible that Rh(III) reacts with imidazole or benzeimidazole?

Offline rolnor

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Re: Can Rhodium(III) react with imidazole?
« Reply #2 on: May 01, 2022, 01:03:19 AM »
I strongly beleive it can not. It can coordinate but not react.

Offline hwg1994

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Re: Can Rhodium(III) react with imidazole?
« Reply #3 on: May 01, 2022, 03:57:11 AM »
I strongly beleive it can not. It can coordinate but not react.
Could u please provide any literature or mechanism about Rh3+ coordinate with imidazole? does Rh3+ similiar to Ru3+?

Offline wildfyr

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Re: Can Rhodium(III) react with imidazole?
« Reply #4 on: May 01, 2022, 07:46:08 PM »
This is an extremely niche topic, have you tried google scholar searching first?

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