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Topic: Hydrogen peroxide quenching  (Read 14430 times)

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Offline mir

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Hydrogen peroxide quenching
« on: November 17, 2006, 07:29:08 AM »
I am looking for a reductant to "kill"/quench my hydrogen peroxide in ethyl acetate, without destroying a quinone in my sample.

Sodium Thiosulphate is to powerful, and reduces the quinone to hydroquinone very easily.
I have thought of Sodium Sulphite, but I need to order it, and there is no time.
Catalase is a protein that is produced commercially, very effective but only works in water solution.
I was thinking of Sodium Nitrite, would that work?
Or maybe a iron compound?

Have you any suggestions?
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Offline Borek

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Re: Hydrogen peroxide quenching
« Reply #1 on: November 17, 2006, 07:55:00 AM »
What about some catalytic decomposition, with - say - MnO2?
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Offline AWK

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Re: Hydrogen peroxide quenching
« Reply #2 on: November 17, 2006, 08:15:59 AM »
Many enzymes (especially immobilized on polymers) also work in organic medium
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Offline mdlhvn

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Re: Hydrogen peroxide quenching
« Reply #3 on: November 19, 2006, 09:12:58 AM »
You want to get quinone? Why do you extract quinone using an appropriate solvent.

Offline Ψ×Ψ

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Re: Hydrogen peroxide quenching
« Reply #4 on: November 22, 2006, 08:18:32 PM »
You want to get quinone? Why do you extract quinone using an appropriate solvent.

Quinones (at least the ones I work with) tend to be painfully insoluble. 

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