April 28, 2024, 11:41:12 AM
Forum Rules: Read This Before Posting


Topic: Naming hydrocarbons  (Read 4227 times)

0 Members and 1 Guest are viewing this topic.

Offline jennielynn_1980

  • Full Member
  • ****
  • Posts: 167
  • Mole Snacks: +8/-4
  • Gender: Female
Naming hydrocarbons
« on: January 10, 2007, 01:16:57 PM »
I am learning to name hydrocarbons and I have these two to name:

a)  CH3 - C = CH - CH2 - CH3
               |
             CH3

For this one I know it's a pentene (5 carbons in longest chain with one double bond at carbon 2)  I know that it has a methyl group on the 2nd carbon.  So would it be called
2-methylpentene-2?

b)                 Cl
                      |
     CH3 - C = C - CH2 - CH3
               |
              Cl

This one I am struggling with because of the chlorine.  We haven't named these ones before.  Because there are 5 carbons in the longest chain and it has one double bond at carbon 2 it is a pentene.  There are chlorines at carbons 2 and 3 so dichloro.  My answer here is
2,3 - dichloropentene - 2.  This one is a BIG guess with the name.

Thanks

Offline enahs

  • 16-92-15-68 32-7-53-92-16
  • Retired Staff
  • Sr. Member
  • *
  • Posts: 2179
  • Mole Snacks: +206/-44
  • Gender: Male
Re: Naming hydrocarbons
« Reply #1 on: January 10, 2007, 01:27:09 PM »
  So would it be called
2-methylpentene-2?

Not quite.
2-methylpent-2-ene
Or
2-methyl-2-pentene


Quote
2,3 - dichloropentene - 2.  This one is a BIG guess with the name.

Not quite, but again same simple mistake (getting the name correct, but writing it wrong following standards). But your reasoning for the name is sound.
2,3-dichloropent-2-ene

But now, ahah! You have a double bond, this means it can be sis or trans (or E-Z if you covered that?)
So now you must determine if the chlorines on the 2nd and 3rd are cis or trans to each other, then tack that on to the beginning of the name. I am assuming you have talked about cis-tran? If not, then just ignore it.

Also, you put some spaces between the dash sometimes, there is not such space following the IUPAC nomenclature standards, at least, not in these cases.
« Last Edit: January 10, 2007, 01:32:23 PM by enahs »

Offline jennielynn_1980

  • Full Member
  • ****
  • Posts: 167
  • Mole Snacks: +8/-4
  • Gender: Female
Re: Naming hydrocarbons
« Reply #2 on: January 10, 2007, 01:42:49 PM »
Okay, so the second one would be trans-2,3-dichloro-2-pentene?

Thanks for the help:)

Offline english

  • Chemist
  • Full Member
  • *
  • Posts: 534
  • Mole Snacks: +31/-10
  • Gender: Male
  • grad student
Re: Naming hydrocarbons
« Reply #3 on: January 10, 2007, 01:54:51 PM »
Okay, so the second one would be trans-2,3-dichloro-2-pentene?

Thanks for the help:)

Yes  ;D

Remember though Jennie that if one side of the alkene double bond has identical substituents, then there cannot be any trans or cis isomerisim. 


For example,

                    Cl
                    |
    CH3 - C = C - CH2 - CH3
               |
              CH3

is niether cis nor trans.




Offline jennielynn_1980

  • Full Member
  • ****
  • Posts: 167
  • Mole Snacks: +8/-4
  • Gender: Female
Re: Naming hydrocarbons
« Reply #4 on: January 10, 2007, 01:56:41 PM »
Thanks for your help :)  and the tip on trans cis isomerism

Sponsored Links