April 18, 2024, 07:11:10 AM
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Topic: Difference between chiral center and chiral carbon  (Read 18855 times)

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Offline Custos

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Re: Difference between chiral center and chiral carbon
« Reply #15 on: January 17, 2007, 09:06:48 PM »
Yes I take your point. I think this is an example of shorthand writing. So when people really mean, say, "the reaction proceeded with adequate regioselectively to give a 90/10 mix of positional isomers" they will write "the reaction gave a 90/10 mixture of regioisomers". I've done this myself many times in describing the regioisomeric outcomes (as opposed to the stereochemical outcomes) of 1,3-dipolar cycloadditions. It's easier but perhaps lazy and imprecise to describe the products as regioisomers.

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Re: Difference between chiral center and chiral carbon
« Reply #16 on: January 18, 2007, 03:47:37 AM »
It's just one of those things where everyone knows what you are talking about but I know some people get offended by it, one professor in particular that I know of, so I try to avoid it.

This thread is the first time that I have heard of someone disagreeing with these other terms like asymmetric synthesis.

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