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Topic: radical effect  (Read 2969 times)

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Offline Alexander

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radical effect
« on: March 24, 2007, 05:56:18 AM »
I can't understand what is "persistent radical effect" :'(
can somebody explain it?
whenever people agree with me, I always feel I must be wrong

Offline mir

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Re: radical effect
« Reply #1 on: March 26, 2007, 04:33:11 PM »
Persistent radicals are radicals with long halftimes, like the molecule TEMPO. Certain radicals are actually unstable, but are kinetically inert because of sterical reasons. Others are specially stabilized by functional groups or through resonance is smeared out throughout the skeleton.

Could you explain where you found this term in use? I will look up in my radical chemistry book as soon as I go working tomorrow :-)
No single thing abides, but all things flow.
Fragment to fragment clings, and thus they grow
Until we know and name them.
Then by degrees they change and are no more
The things we know.
- Titus Lucretius Carus

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