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Topic: DIBAH  (Read 3690 times)

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Offline derster

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DIBAH
« on: May 05, 2007, 10:02:04 PM »
Can someone please provide the major organic product which results when (CH3)2-CH-CH2-CH2-COCl is treated with DIBAH.

Offline refid

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Re: DIBAH
« Reply #1 on: May 05, 2007, 11:44:38 PM »
 well i know ester become aldehyde when treated with DIBAH... i assume since the acyl chloride is the most reactive, would probably go to the primary alcohol.. just guess

Offline Dolphinsiu

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Re: DIBAH
« Reply #2 on: May 06, 2007, 03:53:10 AM »
(CH3)2-CH-CH2-CH2-COCl + DIBAL-H

--> RCOCl + DIBAL (Rewrite)
         
        +O --Al (i-Bu)2
          ll     l
--> R - C    H         
            \
            Cl

          O                         OH
          ll        DIBAL-H        l
--> R - C - H      -->      R - C - H
                                      l
                                      H

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