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Topic: How to name nitro equivalent of an enolate  (Read 4661 times)

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Offline GlowingApple

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How to name nitro equivalent of an enolate
« on: May 09, 2007, 07:34:48 PM »
Hi, I'm trying to determine how to name an intermediate I'm working with.  A general structure is at http://www.kempinger.us/bin/nitro_ion.gif.  It's the nitro equivalent of an enolate, but I'm not sure what name it would take.

Any ideas what to call it?
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Offline hmx9123

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Re: How to name nitro equivalent of an enolate
« Reply #1 on: May 11, 2007, 01:27:34 AM »
Hmm.  Perhaps it's some sort of oxime-derived name?  I dunno.  You've got one interesting compound, though. :)
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Offline sjb

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Re: How to name nitro equivalent of an enolate
« Reply #2 on: May 11, 2007, 05:28:49 AM »
Quote from: GlowingApple on May 09, 2007, 07:34:48 PM
It's the nitro equivalent of an enolate, but I'm not sure what name it would take.
Any ideas what to call it?

I think you may be able to call it a nitronate - see eg Anderson's work on the nitro Mannich reaction http://dx.doi.org/10.1021/jo048304h ?

S
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Offline alphahydroxy

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Re: How to name nitro equivalent of an enolate
« Reply #3 on: May 11, 2007, 06:10:23 AM »
how about an oximium ion? Or maybe an N-oxo-oximium? Wild guess really, but report back if you do find out!
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