Chemical Forums
1 Hour
1 Day
1 Week
1 Month
Forever
April 30, 2024, 11:50:30 PM
Forum Rules
: Read This Before Posting
Home
Help
Search
Login
Register
Chemical Forums
Chemistry Forums for Students
Organic Chemistry Forum
Mercuration
« previous
next »
Print
Pages: [
1
]
Go Down
Topic: Mercuration (Read 3470 times)
0 Members and 1 Guest are viewing this topic.
redfox
Regular Member
Posts: 62
Mole Snacks: +1/-0
Mercuration
«
on:
May 10, 2007, 02:19:59 PM »
I'm confused. I'm making 3-trimethylsilylthiophene and an isomer or 2-trimethylsilylthiophene. Suddenly I'm told we're introducing mercury into the equation...I'm not sure why, maybe just to see how it reacts...but the problem is that it's impossible to detect by NMR spectroscopy so must be replaced with Iodine as it acts in the same way and doesn't interfere with anything else. I don't see why mercury would be used in the first place as it'll only be removed, and also. I'm told that it was used a lot way back when but has been almost forgotten about now, which is why I'm to use it...but I dont' know of the benefits of using it. I've tried looking it up but there seems to be nothing on the net and nothing in text books!
Any ideas??
Tis my last question tonight...honestly!
Logged
movies
Organic Minion
Retired Staff
Sr. Member
Posts: 1973
Mole Snacks: +222/-21
Gender:
Better living through chemistry!
Re: Mercuration
«
Reply #1 on:
May 10, 2007, 08:01:03 PM »
199
Hg and
201
Hg are both naturally abundant (17% and 13%, respectively) and are both NMR active nuclei (spin 1/2 and 3/2, respectively). So you can observe Hg by NMR!
Logged
Print
Pages: [
1
]
Go Up
« previous
next »
Sponsored Links
Chemical Forums
Chemistry Forums for Students
Organic Chemistry Forum
Mercuration