June 15, 2024, 05:58:51 PM
Forum Rules: Read This Before Posting


Topic: can you figure out the below reaction's product  (Read 3236 times)

0 Members and 1 Guest are viewing this topic.

Offline jimmyapex

  • Regular Member
  • ***
  • Posts: 30
  • Mole Snacks: +0/-0
  • Gender: Male
can you figure out the below reaction's product
« on: August 07, 2007, 04:52:03 AM »
what are the final reaction product for the below hydrogenation

1.  reactant:3-nitrobenzaldehyde
     product:3-aminobenzaldehyde or 3-nitrobenzyl alcohol or 3-aminobenzyl alcohol?

2.  Reactant:RCOR'
     Product:RCHOHR' or RCH2R' ?

Custom Synthesis&Scale-up Service
MSN/Email:jimmy_ahchem@hotmail.com

Offline sjb

  • Global Moderator
  • Sr. Member
  • ***
  • Posts: 3653
  • Mole Snacks: +222/-42
  • Gender: Male
Re: can you figure out the below reaction's product
« Reply #1 on: August 07, 2007, 04:11:24 PM »
Depending on the conditions, any one of the different reduction products may be preferentially formed.

For instance, things like NaBH4 will convert ketones to secondary alcohols, but Wolff-Kishner will take the ketone right down to the methylene.

Look up "chemoselectivity".

S

Sponsored Links