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Topic: magnesium and sulfur  (Read 4079 times)

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Offline crazy4laptops

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magnesium and sulfur
« on: September 15, 2007, 09:46:35 PM »
1st experiment, what does it take to get a strip of magnesium lit? Will it take alot of heat, or just a match?

2nd experiment-
I read in the uncle tungsten book. he put a rose over burning sulfur, the color disappeared and when he put the rose in water, the color returned.

questions- will this work at all? If it does, how? How do you get sulfur to burn? What should I burn the sulfur in? And how far away from the flame do I hold the rose?

thanks,

-Ben

Offline shelanachium

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Re: magnesium and sulfur
« Reply #1 on: September 16, 2007, 03:33:26 PM »
Mg/O2 reaction takes a lot of heat to start, a feeble match is usually insufficient. Must be held in a hot flame for quite a while, but once going very energetic indeed!

Mg is difficult to get to burn because of hard protective oxide layer (cf Al); this is why both metals, both highly reactive, can be used as engineering metals. Both must melt so oxide layer breaks before they will burn - so usually match won't do.

Sulfur is easy to ignite indeed, a feeble match will indeed do. Sulfur has a low melting and boiling point. It mostly yields sulfur dioxide SO2, which is a reducing agent because it is easily oxidised to sulfuric acid H2SO4. Many flower pigments lose their colour when reduced, which is why Oliver Sacks in 'Uncle Tungsten' found rose-petals were bleached when exposed to the reducing agent SO2 from burning sulfur. Exposure to water (more precisely, oxygen dissolved in the water) reoxidised the bleached pigment and restored the colour.

I'd put rose and burning sulfur in same enclosed container (SO2 choking and toxic) and rose should be damp, so SO2 can dissolve in water film. Much easier to oxidise SO2 + H2O 'H2SO3' to H2SO4 than SO2 to SO3.

Offline crazy4laptops

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Re: magnesium and sulfur
« Reply #2 on: September 17, 2007, 01:19:03 PM »
a few more questions-

how much sulfur do I need to bleach the rose?

How fast is the reaction?

also, does magnesium burn underwater?

i tried getting sulfur powder to light with a match, and it just melted, it didn't burn. What needs to be done in order to get sulfur to burn?
« Last Edit: September 19, 2007, 01:14:17 PM by crazy4laptops »

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