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Offline claudia

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analytical chemistry question
« on: October 08, 2007, 12:03:59 AM »
Hello there! i am struggling over this problem here...hopefully someone could take a look at it and help  me out :)

1. What percent of iron is there an iron ore containing Fe3O4 is 0.2824g of ore gave 0.0917g of Fe2O3 by gravimetric analysis?

2. What percent of the ore was Fe3O4?



I came up with this answer:  ::)
{ 55.85/[3(55.85)+4(16.00)] }* 100 =24.12% of Fe

{ 16.00/[3(55.85)+4(16.00)] }*100=6.91% O

--> 24.12+6.91=31.03% so 100%-31.03%=68.97% of ore?
does this make sense? can anyone help me out i am extremely lost and confused...?? ???
i would really greatly appreciate it.... ???
Claudia :)

Offline enahs

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Re: analytical chemistry question
« Reply #1 on: October 08, 2007, 12:18:59 PM »
M.W. Fe2O3 ~159g/mol

~55.8 g/mol Fe * 2 = ~111.6 g/mol Fe in Fe2O3
(~111.6/~159)*100 = ~70.2% Fe in Fe2O3.
0.702*0.0917g Fe2O3 = ~0.065 g Fe in the collected Fe2O3

There is no more then ~0.065g total, so for question 1.
(~0.065g/0.2842)*100 = ~22.9%


~0.065g Fe * 1mol Fe/ ~55.8 g = ~1.2 x 10-3 mol Fe

~1.2 x 10-3 mol Fe * 1 mol Fe3O4  = ~3.9 x 10-4 mol Fe3O4
                             3 mol Fe

~3.9 x 10-4 mol Fe3O4 * ~231.4g/mol = ~0.09 g Fe3O4

(~0.09 g Fe3O4 / 0.2842 g) * 100 =~31.8%



There are many ways to work it, and many I would consider a lot easier (i.e. a lot less teps). But that is not to hard and hopefully you can follow it.

I of course rounded a lot and was not very precise, so you have to redo the work.




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