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Topic: Alkyl chloride preparation...  (Read 4037 times)

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Offline Door 218

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Alkyl chloride preparation...
« on: October 10, 2007, 06:04:13 AM »
Should the SOCl2-C6H5N system be used specifically for methyl or primary alcohols?  HCl(aq) wouldn't work, right? 
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Offline AWK

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Re: Alkyl chloride preparation...
« Reply #1 on: October 10, 2007, 06:18:20 AM »
Gaseous HCl (not water solution) would work for hight boiling alcohols (from 5 carbon atoms)
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AWK

Offline Door 218

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Re: Alkyl chloride preparation...
« Reply #2 on: October 10, 2007, 04:08:50 PM »
Okay.  So if I want only the monochloro derivative of methanol, SOCl2-C6H5N system is the approach?  Same for primary alcohol?  Makes sense, 'cept the HCl(g) approach for high-boiling primary alcohols...
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Offline technologist

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Re: Alkyl chloride preparation...
« Reply #3 on: October 11, 2007, 12:21:40 AM »
Any Industrial Method for chlorination of C1, C2...., C5 Alchols.
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