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Topic: 2,4 di tert butylphenol  (Read 3918 times)

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Offline rose

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2,4 di tert butylphenol
« on: January 06, 2008, 06:28:22 AM »
HI! Can somebody tell me a good paper about oxidation of 2,4-di-tert-butylphenol? Thanks

Offline Kryolith

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Re: 2,4 di tert butylphenol
« Reply #1 on: January 06, 2008, 06:55:56 AM »
Try to look at this article or its references:

J. Am. Chem. Soc., 125 (36), 11027 -11033

Which oxidation product do you expect?

Offline rose

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Re: 2,4 di tert butylphenol
« Reply #2 on: January 07, 2008, 06:05:21 AM »
Thanks for the reference.
Theoretically, I expect a C-C coupled bisphenol product. Unfortunately, I can not find references (except that you indicated) for this reactions but only for 2,6-di-tert-butylphenol oxidation (which leads to diphenoquinone when oxidizing).

Offline adam

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Re: 2,4 di tert butylphenol
« Reply #3 on: January 07, 2008, 08:48:46 AM »
Hi, see the experimental section of this paper:

Adv. Synth. Catal. 2004, 346, 993-1003

Happy new year.

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