April 28, 2024, 11:11:47 PM
Forum Rules: Read This Before Posting


Topic: covalent/ionic acid confusion  (Read 4948 times)

0 Members and 1 Guest are viewing this topic.

Offline dancool

  • New Member
  • **
  • Posts: 6
  • Mole Snacks: +0/-0
covalent/ionic acid confusion
« on: December 27, 2007, 07:38:46 PM »
i am led to beleieve that in an acid there are H+ ions.

In the HCl atom, this is a covalent structure, yet not purely covalent due to differences in electronegativities, so the chlorine atom takes a bigger share of the shared pair of electrons, making it slightly negative meaning the hydrogen is slightly positive. is this correct.

so if this HCl is now aqeous, what happens? isn't there just molecules of HCl dissolved in water? where are the H+ ions?

thanks

Offline Mitch

  • General Chemist
  • Administrator
  • Sr. Member
  • *
  • Posts: 5298
  • Mole Snacks: +376/-3
  • Gender: Male
  • "I bring you peace." -Mr. Burns
    • Chemistry Blog
Re: covalent/ionic acid confusion
« Reply #1 on: December 27, 2007, 07:49:00 PM »
HCl fully dissociates to H+ and Cl- in water.
Most Common Suggestions I Make on the Forums.
1. Start by writing a balanced chemical equation.
2. Don't confuse thermodynamic stability with chemical reactivity.
3. Forum Supports LaTex

Offline Yggdrasil

  • Retired Staff
  • Sr. Member
  • *
  • Posts: 3215
  • Mole Snacks: +485/-21
  • Gender: Male
  • Physical Biochemist
Re: covalent/ionic acid confusion
« Reply #2 on: December 27, 2007, 08:04:42 PM »
I think its more correct to say that HCl reacts with water because HCl is a stronger acid than H3O+ (or equivalently, water is a stronger base than chloride):

HCl + H2O --> H3O+ + Cl-

Offline AWK

  • Retired Staff
  • Sr. Member
  • *
  • Posts: 7979
  • Mole Snacks: +555/-93
  • Gender: Male
Re: covalent/ionic acid confusion
« Reply #3 on: December 28, 2007, 01:24:09 AM »
I think its more correct to say that HCl reacts with water because HCl is a stronger acid than H3O+ (or equivalently, water is a stronger base than chloride):

HCl + H2O --> H3O+ + Cl-

Dissociation - Arrhenius
protolysis (reaction with base, in this case - water) - Bronsted
but we are discuss about the same process.
AWK

Offline dancool

  • New Member
  • **
  • Posts: 6
  • Mole Snacks: +0/-0
Re: covalent/ionic acid confusion
« Reply #4 on: December 28, 2007, 04:52:29 PM »
so just for clarification:

HCl acid, the molecules/ions present are: H+ ions, Cl- ions and water molecules?


so what is the case for sulphuric acid, do you just get H+ ions and negative sulphate ions?



Offline Mitch

  • General Chemist
  • Administrator
  • Sr. Member
  • *
  • Posts: 5298
  • Mole Snacks: +376/-3
  • Gender: Male
  • "I bring you peace." -Mr. Burns
    • Chemistry Blog
Re: covalent/ionic acid confusion
« Reply #5 on: December 29, 2007, 01:48:41 PM »
yes
Most Common Suggestions I Make on the Forums.
1. Start by writing a balanced chemical equation.
2. Don't confuse thermodynamic stability with chemical reactivity.
3. Forum Supports LaTex

Offline AWK

  • Retired Staff
  • Sr. Member
  • *
  • Posts: 7979
  • Mole Snacks: +555/-93
  • Gender: Male
Re: covalent/ionic acid confusion
« Reply #6 on: December 31, 2007, 01:04:30 AM »



so what is the case for sulphuric acid, do you just get H+ ions and negative sulphate ions?



H2SO4 dissociate fully only on the first step of dissociation
H2SO4 + H2O = H3O+ + HSO4-
Then H2SO4 partially dissocite on the second step
HSO4- + H2O = H3O+ + SO42-
Only at the concentrations lower than ~10-3 M sulfuric acid can be treated as fully dissociated.

Edit: formatting corrected.
« Last Edit: December 31, 2007, 06:43:11 AM by Borek »
AWK

Sponsored Links