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Topic: hydrocarbon bonding heavier than water  (Read 4553 times)

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Offline sandmanou812

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hydrocarbon bonding heavier than water
« on: March 04, 2008, 10:43:00 PM »
I'm looking for something inexpensive that will easily bond with hydrocarbons but has a higher specific gravity than water.  I'm doing research on a chemical additive that would be insoluble in H2O and would increase specific gravity of hydrocarbons for the oil and gas industry for a research project.  I have looked at phenols (carbolic acid), but they seem to be to toxic for my purposes.  I also looked at DMSO, but any Ideas would be much appreciated!

Offline Yggdrasil

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Re: hydrocarbon bonding heavier than water
« Reply #1 on: March 04, 2008, 11:31:28 PM »
Halogenated organic solvents (e.g. dichloromethane) are more dense than water and should dissolve in hydrocarbons.

Offline Transmutation

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Re: hydrocarbon bonding heavier than water
« Reply #2 on: March 09, 2008, 06:49:56 AM »
Halogenated organic solvents (e.g. dichloromethane) are more dense than water and should dissolve in hydrocarbons.

I think you'll just get a triphasic layer with DCM/water/alkanes.  I've certainly seen it happen before in a separatory funnel.

Also, DCM is a suspected carcinogen.  If the toxicity of phenol is bothersome to him it is unlikely that DCM or other haloalkanes will be useful to him.

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