You were a little vague as to the application. Is it for some kind of surface catalysis? Is it for some kind of photonic or RF reflection? Is it just ornamental? If it's either of the latter two, then there are lots of other metals that can be applied, either with Chemical Vapor Deposition (CVD), Vacuum Sputtering, or other means.
Any company that does metallizing for sunglasses, helmet visors, digital discs and the like should probably be able to help you out. Ultramet (Pacoima, CA.) has been applying Platinum Group Metals with CVD longer than anybody, and has quite a bit of experience with catalytic coatings, if this is what you need.