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Topic: Chemical Kinetics Question  (Read 17369 times)

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Offline pnblwzrd

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Chemical Kinetics Question
« on: April 20, 2008, 04:21:05 PM »
Im having a lot of trouble with this question:
4.  The decomposition of hydrogen peroxide is catalyzed by iodide ion.  The
   Catalyzed reaction is thought to proceed by a two-step mechanism:
H2O2(aq)   +   I-(aq)   →   H2O(l)   +   IO-(aq)                   (slow)
IO-(aq)   +   H2O2(aq)   →   H2O(l)   +   O2(g)   +   I-(aq)     (fast)
   (a)  Write the rate law for each of the elementary reactions of the mechanism.
   (b)  Write the chemical equation for the overall reaction.                                
   (c)  Identify the intermediate, if any, in the mechanism 
   (d)  Assuming that the first step of the mechanism is rate determining, predict the
           rate law for the overall process. 
I know the overall reaction is 2 H2O2 -> 2 H2O + O2 (or at least i think I know) but other than that I don't really know what to do or how to identify and intermediate.
Any help?

Offline nj_bartel

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Re: Chemical Kinetics Question
« Reply #1 on: April 20, 2008, 07:28:54 PM »
Do you know what a catalyst is?  What are the components of a catalyzed reaction?  How did you find the overall reaction?

Offline pnblwzrd

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Re: Chemical Kinetics Question
« Reply #2 on: April 20, 2008, 07:35:20 PM »
thats all the information

Offline nj_bartel

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Re: Chemical Kinetics Question
« Reply #3 on: April 20, 2008, 09:42:58 PM »
I know that's all the information directly associated with the problem.  My question refer to background knowledge you should have in order to be able to solve that problem.

Offline pnblwzrd

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Re: Chemical Kinetics Question
« Reply #4 on: April 20, 2008, 11:09:35 PM »
you aren't really helping by asking me questions.

Offline nj_bartel

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Re: Chemical Kinetics Question
« Reply #5 on: April 21, 2008, 01:03:17 AM »
The answer to A, B, C, and D are all 72 K  ;D

Offline Astrokel

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Re: Chemical Kinetics Question
« Reply #6 on: April 21, 2008, 09:28:00 AM »
Im having a lot of trouble with this question:
4.  The decomposition of hydrogen peroxide is catalyzed by iodide ion.  The
   Catalyzed reaction is thought to proceed by a two-step mechanism:
H2O2(aq)   +   I-(aq)   →   H2O(l)   +   IO-(aq)                   (slow)
IO-(aq)   +   H2O2(aq)   →   H2O(l)   +   O2(g)   +   I-(aq)     (fast)
   (a)  Write the rate law for each of the elementary reactions of the mechanism.
   (b)  Write the chemical equation for the overall reaction.                                
   (c)  Identify the intermediate, if any, in the mechanism 
   (d)  Assuming that the first step of the mechanism is rate determining, predict the
           rate law for the overall process. 
I know the overall reaction is 2 H2O2 -> 2 H2O + O2 (or at least i think I know) but other than that I don't really know what to do or how to identify and intermediate.
Any help?

a) r= k[reactant]^n
b) right
c) Substances generated by one step and used for the succeeding step are considered intermediates.
d) The order of the concentration of the reactant in the overall rate law is the stoichiometric coefficient of the particular reactant in the rate determing step.

For example, rate determing step:  2A + B --> C
                                 
Therefore, the overall rate law is r = k[A]^2[B ]
No matters what results are waiting for us, it's nothing but the DESTINY!!!!!!!!!!!!

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