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Topic: % Yield with a saturated reactant?  (Read 4068 times)

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Offline Kabraxis

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% Yield with a saturated reactant?
« on: May 01, 2008, 06:11:16 PM »
Hi. :)

In my lab we synthesized:
K3Fe(C2O4)3•3H2O from:

10g Fe(NH4)2(SO4)2•6H2O and
50mL 1M H2C2O4 and
1mL 3M H2SO4 and
20mL K2C2O4 (saturated at 40°C) and
40mL 3% H2O2 and
20mL C2H5OH

And I am supposed to calculate the % yield of the K3Fe(C2O4)3•3H2O crystals (ended up with 4.102g) but the saturated potassium oxalate has me thrown off. I'm not sure what saturation means as far as molarity and so I'm not sure exactly how much is in there.

Any help is appreciated, thanks!

Offline Arkcon

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Re: % Yield with a saturated reactant?
« Reply #1 on: May 01, 2008, 06:24:45 PM »
If you must figure out the % yield based on potassium oxalate, then you'll simply have to look up what g/L a saturated solution of potassium oxalate.  The question for me is, which reactant should you use to figure out % yield?  It should be the limiting reactant, and I don't know exactly which one that is.
Hey, I'm not judging.  I just like to shoot straight.  I'm a man of science.

Offline Kabraxis

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Re: % Yield with a saturated reactant?
« Reply #2 on: May 01, 2008, 09:13:01 PM »
Ah... I feel dumb, the LR is the 10g Fe compound, so nevermind about the whole saturated thingy. Thanks for helping me have this realization though! :D

Offline AWK

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Re: % Yield with a saturated reactant?
« Reply #3 on: May 02, 2008, 01:20:51 AM »
You should find data for solubility of K2C2O4 at 40°C before check for a limiting reagent or calculate yield assuming Mohr's salt is a limiting reagent
AWK

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