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Conversion of bromobenzenes to anilines, phenols and carboxylic acid
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Topic: Conversion of bromobenzenes to anilines, phenols and carboxylic acid (Read 7336 times)
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zq
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Conversion of bromobenzenes to anilines, phenols and carboxylic acid
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May 06, 2008, 12:46:52 AM »
Can anybody suggest ways to convert bromobenzenes to anilines, phenols and carboxylic acid?
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zq
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Re: Conversion of bromobenzenes to anilines, phenols and carboxylic acid
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May 06, 2008, 01:17:45 AM »
For anilines, Pd catalyzed bromo to amine substitution is known. Carboxylic acids can be obtained by Pd or Ni catalyzed carbonylations? Are any other methods available for the above transformations?
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affa
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Re: Conversion of bromobenzenes to anilines, phenols and carboxylic acid
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May 06, 2008, 01:48:47 AM »
for making benzoic acid from bromobenzenes, carboxylation of the Grignard reagent, PhMgBr, with CO2 is much cheaper and safer method than transition-metal catalyzed carbonylation (using CO).
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Conversion of bromobenzenes to anilines, phenols and carboxylic acid