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Topic: Conjugate base causing increased acidity of a solution?  (Read 4492 times)

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Offline spirochete

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Conjugate base causing increased acidity of a solution?
« on: August 23, 2008, 09:11:42 PM »
Why does the addition of the conjugate base of a strong acid, such as SO42-, increase the acididity of a solution?  If there are no protons there how can it make things more acidic?

This question has its roots in biochemistry/microbial ecology but technically it's most related to inorganic chemistry.  For example, microbes which reduce sulfate to sulfite and/or sulfide are important in bioremediation of acid mine drainage sites.  Although sulfide is a fairly strong acid it's also volatile and thus dissipates from the environment easily.  Sulfide oxidizers worsen the situation for obvious reasons.

Offline Yggdrasil

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Re: Conjugate base causing increased acidity of a solution?
« Reply #1 on: August 23, 2008, 11:12:20 PM »
SO42- is the conjugate base of a weak acid (HSO4- and thus acts as a weak base).  HSO4- itself is a conjugate base of a strong acid, but is acidic because it can form SO42-.

I think the answer may have more to do with the biochemistry.  Is it possible that the oxidation/reduction of these sulfur oxyanions consumes/releases H+?

Offline spirochete

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Re: Conjugate base causing increased acidity of a solution?
« Reply #2 on: August 25, 2008, 12:25:07 AM »
Now that you mention it that sounds more correct.  Thanks for the idea. 

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